Electronegativity Calculator

Compare two Pauling electronegativity values to estimate bond polarity and likely bond character.

Electronegativity difference
Enter the Pauling values for the two bonded atoms.

About electronegativity and bond polarity

Electronegativity measures how strongly an atom attracts shared electrons when it participates in a chemical bond. Linus Pauling developed the best-known relative scale, on which fluorine has the highest value. Values generally increase from left to right across a period and decrease down a group. The difference between the electronegativities of two bonded atoms offers a useful first estimate of how evenly their bonding electrons are distributed. This calculator subtracts one Pauling value from the other and reports the absolute difference. A difference up to 0.40 is commonly described as nonpolar covalent, because the pair shares electron density fairly evenly. Differences above 0.40 and through 1.70 are classified as polar covalent. One atom attracts the shared density more strongly and develops a partial negative charge, while its partner develops a partial positive charge. A difference above 1.70 is labeled predominantly ionic, indicating substantial electron transfer character. These boundaries are teaching conventions rather than sharp physical laws. Bonding forms a continuum, and a compound's observed properties depend on more than one pair of isolated atoms. Oxidation state, molecular geometry, resonance, coordination, crystal structure, and the surrounding chemical environment can all modify charge distribution. Some metal and nonmetal combinations with large differences retain measurable covalent character, while strongly polarized covalent bonds can behave ionically in a solvent. Bond polarity also differs from molecular polarity. A molecule can contain polar bonds yet have no net dipole if its geometry makes the individual bond dipoles cancel. Carbon dioxide is the familiar linear example. Water has polar oxygen-hydrogen bonds and a bent shape, so its dipoles reinforce one another. Use electronegativity difference to analyze each bond first, then consider the complete three-dimensional arrangement before describing the molecule. The tool is useful for predicting partial-charge direction, comparing bond types, studying intermolecular forces, and checking introductory chemistry exercises. Enter values from the same electronegativity scale for a meaningful comparison. For quantitative bond moments, spectroscopy, or unusual compounds, use measured data or a more detailed electronic-structure model instead of treating the classification threshold as an exact experimental result.

Electronegativity examples

Bond and valuesDifference and typeInterpretation
H 2.20 and Cl 3.160.96, polar covalentElectron density is drawn toward chlorine.
Na 0.93 and Cl 3.162.23, predominantly ionicThe large difference supports strong ionic character.
C 2.55 and H 2.200.35, nonpolar covalentThe carbon-hydrogen bond is weakly polarized.

How to compare electronegativity

  1. Look up both atoms on a Pauling electronegativity table.
  2. Enter each value in its corresponding field.
  3. Select Analyze bond to calculate the absolute difference.
  4. Use the reported class as a guide, then consider molecular geometry.

Electronegativity calculator FAQ

Which electronegativity scale should I use?

Use Pauling values for both entries, as this tool's thresholds follow that scale. Mixing scales makes the difference difficult to interpret.

Is a difference of 1.7 always ionic?

No boundary makes bonding suddenly change character. The 1.7 threshold is a convenient introductory guideline for a continuous physical property.

Which atom carries the partial negative charge?

The atom with the higher electronegativity attracts more bonding electron density. It is therefore assigned the partial negative end of the bond dipole.

Can a molecule with polar bonds be nonpolar?

Yes, bond dipoles can cancel in a symmetric molecular geometry. Molecular polarity requires considering both bond polarity and three-dimensional shape.

Why does electronegativity change across the periodic table?

Increasing effective nuclear charge generally strengthens attraction across a period. Greater distance and electron shielding generally weaken attraction down a group.