Boiling Point Calculator
Estimate how a liquid's boiling temperature changes with pressure using the Clausius-Clapeyron equation.
About boiling point and pressure
Boiling point examples
| Inputs | Estimated result | Context |
|---|---|---|
| Water: 100 °C at 101.325 kPa; target 80 kPa; 40.65 kJ/mol | About 93.4 °C | Reduced pressure lowers water's boiling temperature. |
| Ethanol: 78.37 °C at 101.325 kPa; target 90 kPa; 38.56 kJ/mol | About 74.9 °C | A modest pressure reduction produces a modest boiling-point decrease. |
| Water: 100 °C at 101.325 kPa; target 150 kPa; 40.65 kJ/mol | About 111.3 °C | Higher pressure raises the estimated boiling point. |
How to calculate a boiling point
- Enter a known boiling temperature for the liquid.
- Enter the pressure associated with that known boiling point.
- Enter the target pressure and the liquid's enthalpy of vaporization.
- Select Calculate boiling point to view the pressure-adjusted estimate.
Boiling point calculator FAQ
Why does boiling point change with pressure?
Boiling begins when a liquid's vapor pressure matches the external pressure. Lower external pressure reaches that condition at a lower temperature, while higher pressure requires more heating.
Can I use different pressure units?
The equation uses a pressure ratio, so any pressure unit works when both values use the same unit. This calculator labels both entries in kPa to prevent accidental mixing.
Where can I find enthalpy of vaporization?
Chemical handbooks, safety data, and trusted thermodynamic databases publish molar enthalpy of vaporization values. Use a value measured near the reference temperature whenever possible.
Does this work for mixtures?
It is intended for a single substance with one representative enthalpy value. Mixtures can have composition-dependent bubble and dew points, so rigorous mixture models are more appropriate.
How accurate is the Clausius-Clapeyron estimate?
It is generally useful across moderate ranges where enthalpy changes little and vapor behavior is close to ideal. Accuracy decreases over wide ranges and near a substance's critical point.